Product ID:AUTOMOTIVE GASOLINE:REGULAR UNLEADED, PREMIUM UNLEADED
MSDS Date:07/01/1992
FSC:9130
NIIN:01-272-0983
MSDS Number: BVHKS

FARMERS UNION CENTRAL EXCHANGE INC (CENEX)

5500 CENEX DRIVE
ST PAUL, MN 55164-0089
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 612-451-5151

Cage: 5Z134

FARMERS UNION CENTRAL EXCHANGE INC

64089 ST PAUL, MN 55164-0089 US

Telephone: 612-451-5151

Cage: 5Z134

GASOLINE (CAS#-MIXTURE).

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM/500STEL;9394

1,2,4-TRIMETHYLBENZENE (SARA III) (PSEUDOCUMENE)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: <12%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9394

HYDROCARBONS (AROMATIC AND PARAFFINIC HYDROCARBONS)

Fraction By Weight: 50-80%

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5%

OSHA PEL SEE 1910.1028

ACGIH TLV: 10 PPM; A2; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-3%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/125STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <2.4%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CUMENE (SARA III)

CAS: 98-82-8

RTECS: GR8575000

Fraction By Weight: <2.0%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 50 PPM; 9394

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10-15%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150STEL;9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10-20%

OSHA PEL 200 PPM; Z-2

ACGIH TLV: S, 50 PPM; 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: <15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHAL:MUC MEMB/THROAT/RESP TRACT
IRRIT.VAP OVEREXPO CAN LEAD TO BRONCHO-PNEUMONIA.HIGH CONC
INHAL:FATAL PULM EDEMA.SKIN:DERM FROM REPEAT/PROLONG
EXPOUSRE,BLISTERING DUE TO DEFATTING.EYES:HYPEREMIA OF
CONJUNCTIVA.INGEST:INEBRIATION,DROW,BLURRED
VISION,VERTIGO,CONF,VOMIT,UNCONSC,CONVUL,CYANOSIS.CHEM PNEU FROM
ASPIRATION.
Explanation of Carcinogenicity:CONTAINS BENZENE (NTP/IARC/OSHA) AND
GASOLINE (IARC).
Effects of Overexposure:SOME STUDIES HAVE INDICATED THAT WORKERS
EXPOSED MANY YEARS TO HIGH CONCENTRATINS OF BENZENE HAVE A HIGHER
INCIDENCE OF LEUKEMIA. BENZENE CAN BE TOXIC TO BLOOD &
BLOOD-FORMING TISSUES. STUDIES W/MICE & RATS HAVE SHOWN SOME PETRO
DISTILLATESCAUSE DAMAGE &/OR TUMORS OF KIDNEYS & LIVER IN THESE
ANIMALS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFG.

First Aid:EYE:PROMPTLY FLUSH W/PLENTY OF RUNNING WATER FOR @ LEAST
15MINS & UNDER EYELIS.CALL DR.SKIN:REMOVE CONTAMIN CLOTH.WASH AREA
W/SAOP & WATER.IRRIT DEVELOPS SEE DR.INHAL:REMOVE TO FRESH
AIR.BREATHING IS DIFFICULT GIVE OXY.BREATHING STOPPED GIVE ARTI
RESP.CALL DR.INGEST:DO NOT INDUCE VOMIT.ASPIRATION HAZ.CALL DR/POIS
CNTRL CNTR.IF CONSC GIVE 2 GLASSES OF WATER.SPONTANEOUS VOMIT LOWER
HEAD BELOW HIPS.

Flash Point Method:TCC
Flash Point:-50F,-46C
Autoignition Temp:Autoignition Temp Text:536F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM. OSHA
CLASS IA FLAMM LIQ.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE TO EXTINGUISH
FIRE.USE WATER SPRAY TO COOL FIRE EXPOSED DRUMS/TANKS TO PREVENT
PRESSURE RUPTURE.WEAR SCBA & FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DANGEROUS FIRE/EXPLO HAZ WHEN EXPOSED TO
HEAT/FLAMES.VAP CAN FLOW ALONG SURFACES REACH DISTANT IGN SOURCES &
FLASHBACK.CAN REACT VIOLENTLY W/OXIZING AGENT.

Spill Release Procedures:REPORT AS REQUIRED TO STATE/LOC AUTHORITIES.IF
REACHES WATERWAYS REPORT TO US COAT GUARD 800-424-8802.REMOVE
SOURCES OF IGN.GET EXPLOS-PROOF VENTI.PROTECTION AGAINST LIQ/VAPOR
EXPOSURE REQUIRED.DISPER SE VAP W/WATERSPRAY.DIKE.ADD ABSORBENT
&PICKUP.
Neutralizing Agent:NONE SPECIFIED BY MFG.

Handling and Storage Precautions:STORE IN CLOSED CNTNRS IN
COOL,DRY,WELL-VENTI AREA AWAY FROM SOURCES OF HEAT/IGN/STRONG
OXIDIZING AGENTS.PROTECT CNTNRS FROM PHYSCIAL DAMAGE.
Other Precautions:AVOID DIRECT SUNLIGHT.STORAGE MUST MEET RQMTS OF OSHA
CLASS IA LIQ & LOC CODE.OUTDOOR/DETACHED STORAGE PREFERRED.NO OPEN
FLAMES/SMOKING IN AREAS OF USE.PREVENT STATIC ELECT SPARKS.USE
EXPLOSION-PROOF ELECTR SERVICES.

Respiratory Protection:APPROPIRATE NIOSH RESP SHOULD BE AVAILABLE FOR
NON-ROUTINE OR EMERGENCY USE WHEN VAPORS ARE ABOVE TLV.
Ventilation:GEN/LOC EXH VENTI (EXPLOSION-PROOF) TO KEEP VAP BELOW TLV
RQMTS IN WORKPLACE.
Protective Gloves:NEOPRENE,RUBBER GLOVES & BOOTS.
Eye Protection:CHEM SAFETY GOGGLES &/OR ULL FACESHIELD
Other Protective Equipment:WEAR PROTECTIVE CLOTHING APPROPRIATE FOR
WORK SITUATION TO MIN SKIN CONTACT.EYEWASH
FOUNTAINS,SHOWERS,WASHING FACILITIES
Work Hygienic Practices:AVOID SKIN CONTACT & INHAL OF VAP.WEAR CLEAN
WORK CLOTHING DAILY.PROVIDE SUITABLE TRAINING TO HANDLERS & WORKERS
OF MATL
Supplemental Safety and Health
STORAGE:INDOOR USE OF MATL REQUIRES EXHAUST VENTI TO REMOVE VAPORS.
BOND/GROUND ALL EQUPMT USED IN TRANSFERRING PRODUCT FROM CNTNR TO
CNTNR TO PREVENT STATIC CHARGE.

HCC:F1
Boiling Pt:B.P. Text:80.0F,26.7C
Vapor Pres:275-475
Vapor Density:3.0-4.0
Spec Gravity:0.71-0.76
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:CLEAR,MOBILE LIQ W/CHARACTER GASOLINE ODOR
RECOGNIZABLE @100PPM IN AIR,MAYBE DY
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:UNDUE EXPOSURE TO AIR, HEAT, FLAME,
SPARKS, STATIC ELECTRICITY, OR ANY IGNITON SOURCE.
Hazardous Decomposition Products:CARBON MONOXIDE & OTHER TOXIC MATLS
FROM COMBUSTION.

Waste Disposal Methods:FOLLOW CURRENT LOCAL, STATE AND FEDERAL
REGULATIONS. BURN SCRAP MATERIAL IN AN APPORVED INCINERATOR. BURN
CONTAMINATED LIQ BY SPRAYING INTO AN INCINERATOR. RQ:PETROLEUM
HYDROCARBONS. CONTAINS TOXIC CH EM SUBJECT TO RELEASE REPORTING
REQMTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.